Chromium(III) Bromide Hexahydrate

SECTION 1. IDENTIFICATION

Product Name: Chromium(III) Bromide Hexahydrate

Product Number: All applicable American Elements product codes, e.g. CR-BR-02-P.6HYD , CR-BR-025-P.6HYD , CR-BR-03-P.6HYD , CR-BR-035-P.6HYD , CR-B-04R-P.6HYD , CR-BR-05-P.6HYD

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CAS #: 13478-06-3

Relevant identified uses of the substance: Scientific research and development

Supplier details:American Elements10884 Weyburn Ave.Los Angeles, CA 90024Tel: +1 310-208-0551Fax: +1 310-208-0351

Emergency telephone number:Domestic, North America: +1 800-424-9300International: +1 703-527-3887

SECTION 2. HAZARDS IDENTIFICATION

Classification of the substance or mixture in accordance with 29 CFR 1910 (OSHA HCS)GHS06 Skull and crossbonesAcute Tox. 3H301 Toxic if swallowed.GHS08 Health hazardResp. Sens. 1 H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled.GHS05 CorrosionSkin Corr. 1B H314 Causes severe skin burns and eye damage.Eye Dam. 1H318 Causes serious eye damage.GHS07Skin Sens. 1H317 May cause an allergic skin reaction.Hazards not otherwise classifiedNo data availableGHS label elementsGHS label elements, including precautionary statementsHazard pictograms

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GHS05 GHS06 GHS08Signal wordDangerHazard statementsH301 Toxic if swallowed.H314 Causes severe skin burns and eye damage.H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled.H317 May cause an allergic skin reaction.Precautionary statementsP260Do not breathe dust/fume/gas/mist/vapors/spray.P301+P310IF SWALLOWED: Immediately call a POISON CENTER/ doctor/…P303+P361+P353 If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.P405Store locked up.P501Dispose of contents/container in accordance with local/regional/national/international regulations.WHMIS classificationD2A – Very toxic material causing other toxic effectsE – Corrosive materialClassification systemHMIS ratings (scale 0-4)(Hazardous Materials Identification System)Health (acute effects) = 2Flammability = 0Physical Hazard = 1Other hazardsResults of PBT and vPvB assessmentPBT:N/AvPvB:N/A

SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

SubstancesCAS No. / Substance Name:13478-06-3 Chromium (III) bromideIdentification number(s):EC number:233-088-6

SECTION 4. FIRST AID MEASURES

Description of first aid measuresGeneral informationImmediately remove any clothing soiled by the product.If inhaled:Supply patient with fresh air. If not breathing, provide artificial respiration. Keep patient warm.Seek immediate medical advice.In case of skin contact:Immediately wash with soap and water; rinse thoroughly.Seek immediate medical advice.In case of eye contact:Rinse opened eye for several minutes under running water. Consult a physician.If swallowed:Seek medical treatment.Information for doctorMost important symptoms and effects, both acute and delayedCauses severe skin burns.Causes serious eye damage.Indication of any immediate medical attention and special treatment neededNo data available

SECTION 5. FIREFIGHTING MEASURES

Extinguishing mediaSuitable extinguishing agentsProduct is not flammable. Use fire-fighting measures that suit the surrounding fire.Special hazards arising from the substance or mixtureIf this product is involved in a fire, the following can be released:Hydrogen bromide (HBr)Advice for firefightersProtective equipment:Wear self-contained respirator.Wear fully protective impervious suit.

SECTION 6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency proceduresUse personal protective equipment. Keep unprotected persons away.Ensure adequate ventilationEnvironmental precautions:Do not allow material to be released to the environment without official permits.Methods and materials for containment and cleanup:Use neutralizing agent.Dispose of contaminated material as waste according to section 13.Ensure adequate ventilation.Prevention of secondary hazards:No special measures required.Reference to other sectionsSee Section 7 for information on safe handlingSee Section 8 for information on personal protection equipment.See Section 13 for disposal information.

SECTION 7. HANDLING AND STORAGE

HandlingPrecautions for safe handlingKeep container tightly sealed.Store in cool, dry place in tightly closed containers.Ensure good ventilation at the workplace.Information about protection against explosions and fires:The product is not flammableConditions for safe storage, including any incompatibilitiesRequirements to be met by storerooms and receptacles:No special requirements.Information about storage in one common storage facility:No data availableFurther information about storage conditions:Keep container tightly sealed.Store in cool, dry conditions in well-sealed containers.Specific end use(s)No data available

SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Additional information about design of technical systems:Properly operating chemical fume hood designed for hazardous chemicals and having an average face velocity of at least 100 feet per minute.Control parametersComponents with limit values that require monitoring at the workplace:Chromium (III) compounds, as Cr mg/m3ACGIH TLV 0.5; A4Belgium TWA 0.5Denmark TWA 0.5Finland TWA 0.01France VME 0.5Japan OEL 0.5Korea TLV 0.5Netherlands MAC-TGG 0.5Norway TWA 0.5Poland TWA 0.5Sweden NGV 0.5United Kingdom TWA 0.5USA PEL 0.5Additional information:No dataExposure controlsPersonal protective equipmentFollow typical protective and hygienic practices for handling chemicals.Keep away from foodstuffs, beverages and feed.Remove all soiled and contaminated clothing immediately.Wash hands before breaks and at the end of work.Avoid contact with the eyes and skin.Maintain an ergonomically appropriate working environment.Breathing equipment:Use suitable respirator when high concentrations are present.Protection of hands:Impervious glovesInspect gloves prior to use.Suitability of gloves should be determined both by material and quality, the latter of which may vary by manufacturer.Eye protection:Tightly sealed gogglesFull face protectionBody protection:Protective work clothing

SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

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Information on basic physical and chemical propertiesAppearance:Form: CrystallineColor: VioletOdor: OdorlessOdor threshold: No data available.pH: N/AMelting point/Melting range: 79 °C (174 °F)Boiling point/Boiling range: No data availableSublimation temperature / start: No data availableFlash point: N/AFlammability (solid, gas)No data available.Ignition temperature: No data availableDecomposition temperature: No data availableAutoignition: No data available.Danger of explosion: Product does not present an explosion hazard.Explosion limits:Lower: No data availableUpper: No data availableVapor pressure: N/ADensity at 20 °C (68 °F): 5.4 g/cm3 (45.063 lbs/gal)Relative densityNo data available.Vapor densityN/AEvaporation rateN/ASolubility in Water (H2O): SolublePartition coefficient (n-octanol/water): No data available.Viscosity:Dynamic: N/AKinematic: N/AOther informationNo data available

SECTION 10. STABILITY AND REACTIVITY

ReactivityNo data availableChemical stabilityStable under recommended storage conditions.Thermal decomposition / conditions to be avoided:Decomposition will not occur if used and stored according to specifications.Possibility of hazardous reactionsNo dangerous reactions knownConditions to avoidNo data availableIncompatible materials:Oxidizing agentsNo data availableHazardous decomposition products:Hydrogen bromide

SECTION 11. TOXICOLOGICAL INFORMATION

Information on toxicological effectsAcute toxicity:Toxic if swallowed.Swallowing will lead to a strong corrosive effect on mouth and throat and to the danger of perforation of esophagus and stomach.LD/LC50 values that are relevant for classification:No dataSkin irritation or corrosion:Causes severe skin burns.Eye irritation or corrosion:Causes serious eye damage.Sensitization:May cause allergy or asthma symptoms or breathing difficulties if inhaled.May cause an allergic skin reaction.Germ cell mutagenicity:No effects known.Carcinogenicity:IARC-3: Not classifiable as to carcinogenicity to humans.ACGIH A4: Not classifiable as a human carcinogen: Inadequate data on which to classify the agent in terms of its carcinogenicity in humans and/or animals.Reproductive toxicity:No effects known.Specific target organ system toxicity – repeated exposure:No effects known.Specific target organ system toxicity – single exposure:No effects known.Aspiration hazard:No effects known.Subacute to chronic toxicity:Chromium powder, chromium (II) and chromium (III) compounds may cause nausea, diarrhea, vomiting, skin and eye irritation and pneumoconiosis. Although less likely than Cr(VI) compounds, the NTP considers all chromium to be potentially carcinogenic.Inorganic bromides may produce depression, emaciation and in severe cases, psychosis and mental deterioration. Bromoderma, a bromide rash, often occurs when bromide inhalation or administration is prolonged. This rash is usually found on the face and resembles acne and furunculosis.Subacute to chronic toxicity:No effects known.Additional toxicological information:To the best of our knowledge the acute and chronic toxicity of this substance is not fully known.

SECTION 12. ECOLOGICAL INFORMATION

ToxicityAquatic toxicity:No data availablePersistence and degradabilityNo data availableBioaccumulative potentialNo data availableMobility in soilNo data availableAdditional ecological information:Do not allow material to be released to the environment without official permits.Do not allow undiluted product or large quantities to reach groundwater, water courses, or sewage systems.Avoid transfer into the environment.Results of PBT and vPvB assessmentPBT:N/AvPvB:N/AOther adverse effectsNo data available

SECTION 13. DISPOSAL CONSIDERATIONS

Waste treatment methodsRecommendationConsult official regulations to ensure proper disposal.Uncleaned packagings:Recommendation:Disposal must be made according to official regulations.Recommended cleansing agent:Water, if necessary with cleansing agents.

SECTION 14. TRANSPORT INFORMATION

UN-NumberDOT, IMDG, IATAUN3260UN proper shipping nameDOTCorrosive solid, acidic, inorganic, n.o.s. (Chromium (III) bromide)IMDG, IATACORROSIVE SOLID, ACIDIC, INORGANIC, N.O.S. (Chromium (III) bromide)Transport hazard class(es)DOTClass8 Corrosive substances.Label8Class8 (C2) Corrosive substancesLabel8IMDG, IATAClass8 Corrosive substances.Label8Packing groupDOT, IMDG, IATAIIIEnvironmental hazards:N/ASpecial precautions for userWarning: Corrosive substancesSegregation groupsAcidsTransport in bulk according to Annex II of MARPOL73/78 and the IBC CodeN/ATransport/Additional information:DOTMarine Pollutant (DOT):NoUN “Model Regulation”:UN3260, Corrosive solid, acidic, inorganic, n.o.s. (Chromium (III) bromide), 8, III

SECTION 15. REGULATORY INFORMATION

National regulationsAll components of this product are listed in the U.S. Environmental Protection Agency Toxic Substances Control Act Chemical substance Inventory.All components of this product are listed on the Canadian Non-Domestic Substances List (NDSL).SARA Section 313 (specific toxic chemical listings)13478-06-3 Chromium (III) bromideCalifornia Proposition 65Prop 65 – Chemicals known to cause cancerSubstance is not listed.Prop 65 – Developmental toxicitySubstance is not listed.Prop 65 – Developmental toxicity, femaleSubstance is not listed.Prop 65 – Developmental toxicity, maleSubstance is not listed.Information about limitation of use:For use only by technically qualified individuals.This product contains chromium and is subject to the reporting requirements of section 313 of the Emergency Planning and Community Right to Know Act of 1986 and 40CFR372.Other regulations, limitations and prohibitive regulationsSubstance of Very High Concern (SVHC) according to the REACH Regulations (EC) No. 1907/2006.Substance is not listed.The conditions of restrictions according to Article 67 and Annex XVII of the Regulation (EC) No 1907/2006 (REACH) for the manufacturing, placing on the market and use must be observed.Substance is not listed.Annex XIV of the REACH Regulations (requiring Authorisation for use)Substance is not listed.Chemical safety assessment:A Chemical Safety Assessment has not been carried out.

SECTION 16. OTHER INFORMATION

Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH). The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. American Elements shall not be held liable for any damage resulting from handling or from contact with the above product. See reverse side of invoice or packing slip for additional terms and conditions of sale. COPYRIGHT 1997-2022 AMERICAN ELEMENTS. LICENSED GRANTED TO MAKE UNLIMITED PAPER COPIES FOR INTERNAL USE ONLY.

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